Synchrotron Mossbauer spectroscopy of powder samples
نویسندگان
چکیده
منابع مشابه
Heterogeneous electron-transfer kinetics with synchrotron 57Fe Mossbauer spectroscopy
In the first known kinetic application of the technique, synchrotron Fe-Mössbauer spectroscopy was used to follow the rate of heterogeneous electron transfer between aqueous reagents and a solid phase containing Fe. The solid, a synthetic Fe-enriched Fe(III)-bearing pyroaurite-like phase having terephthalate (TA) in the interlayer [Mg3Fe(OH)8(TA)0.5 2H2O], was reduced by Na2S2O4 and then reoxid...
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VIII VI IV Aenigmatite, Na4 (Fe2 +,Ti,Fe 3 +) 1 2 (SiFe 3 +) 12 0 40 , is a common constituent of sodium-rich alkaline igneous rocks and is classified as an open-branched single-chain silicate, whose structure is closely related to that of sapphirine. The first Mossbauer spectra of three valid aenigmatite specimens were recorded and the detailed crystal chemistry were obtained. In the Mossbauer...
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~ong the easy axis a at 4.2 K induces phase transi tionsatHI =39 kOe andH2 =46 kOe [1-3]. In this ~t1er we report the use of Mossbauer spectroscopy in external magnetic fields to study the magnetic struc (ure of each of the three phases. Previous Mossbauer work in FeCI2 · 2HZ0 includes apower study by Chandra and Hoy [4] and a single z crystal study by Johnson [5]. They found a magnetic o hyp...
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Using recoilless Mossbauer spectroscopy methods, we investigate the atomic absorption spectra of the 14.4keV transition in Fe compounds. The natural linewidth of this transition is determined to the correct order of magnitude with χν = .75. Hyperfine energy shifts in iron oxide and iron sulfate are investigated and measured. The ratio of ground and excited state magnetic moment in Fe is found t...
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Polycrystalline tris-odium vanadium(III) nitridotriphosphate, Na3V(PO3)3N, was prepared by thermal nitridation of a mixture of NaPO3 and V2O5. The title compound is isotypic with Na3Al(PO3)3N. In the crystal, the P-atom and the three O-atom sites are on general positions, whereas the Na-, V- and N-atom sites are located on threefold rotation axes. The P atom is coordinated by three O atoms and ...
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ژورنال
عنوان ژورنال: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
سال: 1995
ISSN: 0168-583X
DOI: 10.1016/0168-583x(94)00743-8